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Nitryl fluoride : ウィキペディア英語版
Nitryl fluoride

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Nitryl fluoride, NO2F, is a colourless gas and strong oxidizing agent, which is used as a fluorinating agent〔Merck Index, 13th edition (2001), p.1193〕 and has been proposed as an oxidiser in rocket propellants (though never flown). It is a molecular species, not ionic, consistent with its low boiling point. The structure features planar nitrogen with a short N-F bond length of 135 pm.〔F. A. Cotton and G.Wilkinson, Advanced Inorganic Chemistry, 5th edition (1988), Wiley, p.333.〕
==Preparation==
Henri Moissan and Lebeau recorded the preparation of nitryl fluoride in 1905 by the fluorination of nitrogen dioxide. This reaction is highly exothermic, which leads to contaminated products. The simplest method avoids fluorine gas but uses cobalt(III) fluoride:
:NO2 + CoF3 → NO2F + CoF2
The CoF2 can be regenerated to CoF3. Other methods have been described.

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